Chen, Jian
jianchen@uwm.eduChemistry Building 631, , ,

Chen, Jian

Associate Professor
Chemistry-Organic

Education

Ph.D., Fudan University

Research Areas

In nature, materials are often created to realize multiple tasks such as mechanical support, sensing, actuation, energy generation, communication, self-healing. Nature’s multifunctional materials are not only active, adaptive, and autonomous, but also efficient and sustainable. My group's research is focused on development of bioinspired smart multifunctional materials for various applications. Depending on specific research projects, students in my group have opportunities to acquire or get exposure to some of the following skills: organic synthesis and characterization, polymer synthesis and characterization, nanomaterials synthesis, functionalization, and characterization, sensor fabrication and characterization, actuator fabrication and characterization, data analysis, problem solving, and communication. After graduation, my former students were hired by employers such as Air Force Research Laboratory, Intel Corporation, Xerion Advanced Battery Corporation, Sigma-Aldrich, Sherwin-Williams, Saint-Gobain. Some of our recent research projects include:

1) IR light-driven soft robots

There has been an increasing interest in the field of bioinspired soft robotics recently. Unlike traditional rigid robots, soft robots can be used for carrying soft, fragile payloads without causing damage and working in cluttered and/or unstructured environments by employing large strain deformation. Liquid crystalline elastomers (LCEs) have fascinated scientists and engineers because they can translate small molecular movements triggered by an external stimulus into large mechanical motions. We have developed a general approach to wavelength-selective, IR light-driven LCE composite-based bilayer hinges that show fast, reversible bending with a large strain. Such composite bilayer hinges can be used in various remote-controlled soft robotic devices such as active origami structures that can reversibly fold and unfold, Venus flytrap-inspired grippers that can pick up delicate objects even under water, and inchworm walkers that can crawl up a hill at a 50-degree incline (See the video below).

Cephalopods, such as cuttlefish, demonstrate remarkable adaptability to the coloration and texture of their surroundings by modulating their skin color and surface morphology simultaneously, for the purpose of adaptive camouflage and signal communication. Inspired by this unique feature of cuttlefish skins, we have developed remote-controlled, smart films that undergo simultaneous changes of surface color and morphology upon IR actuation. We have also demonstrated a remote-controlled inchworm walker that can directly couple a color-changing skin with the robotic movements (See the figure below).

2) Reprogrammable Chemical 3D Shaping

Shape engineering is crucial for controlling the properties and functions of polymers, such as surface roughness, adhesion and wettability, pore size and connection, chirality, and responsiveness towards environmental stimuli, which enable a broad range of applications. We have developed a strategy for shape-reprogramming in a single polymer material called Nafion, which not only allows shape-encoding and 3D translation of encoded geometric information, but also enables erasing and re-encoding of shape information via reversible localized chemical patterning on the same piece of polymer. In essence, our shape-reprogrammable polymer acts as computer hardware that can be reformatted and reprogrammed repeatedly (See the figure and video below). Such reprogrammable chemical 3D shaping technology allows Nafion films to be repurposed directly without going through material disposal and recycling.

3) Stimuli-Responsive Interference Coloration for Sensing and Actuation

The bioinspired stimuli‐responsive structural coloration has received great interest from the scientific and engineering communities in the past two decades, and it offers a wide range of promising applications in medical diagnostics, advanced packaging, environmental and building monitoring, adaptive camouflage, intelligent coatings and textiles, and anticounterfeiting. Because of its design simplicity, thin film interference represents a promising solution toward scalable and affordable manufacturing of high‐quality responsive structural coloration systems. However, thin films of polymers with appropriate thickness generally do not exhibit visible structural colors if they are directly deposited on transparent substrates such as glass, or flexible and stretchable substrates such as polydimethylsiloxane. We have recently developed a versatile new strategy that enables scalable and affordable manufacturing of stimuli-responsive interference coloration (RIC) systems using any substrates. We have demonstrated real‐time, continuous, colorimetric RIC sensors for humidity, organic vapor, mechanical strains, temperature, and certain chemicals by using various stimuli‐responsive polymers (See figures below). The main advantages of such RIC sensors include low cost; zero power consumption; spatial and temporal resolution; and fast, dynamic, and reversible response. Since a vast number of stimuli-responsive polymers and composites are available with rich chemistry, it is possible to significantly expand the RIC systems with new properties and functions, which will open the door to many application possibilities.

Selected Awards

  • NASA Space Act Award, 2008
  • Graduate School/UWM Foundation Research Award, 2007
  • NASA Space Act Tech Brief Award, 2007
  • Best 25 Micro- and Nanotechnologies, 2006; R&D 100 Award, 2005.

Selected Publications

Momtaz, Milad, and Chen, Jian. “High-Performance Colorimetric Humidity Sensors Based on Konjac Glucomannan.” ACS APPLIED MATERIALS \& INTERFACES 12.48 (2020): 54104-54116.
Oyefusi, Adebola, and Chen, Jian. “Mechanical approaches to dynamic, reversible mechanochromism based on thin film interference.” APPLIED MATERIALS TODAY 20. (2020): 100774.
Banisadr, Seyedali, Oyefusi, Adebola, and Chen, Jian. “A Versatile Strategy for Transparent Stimuli-Responsive Interference Coloration.” ACS APPLIED MATERIALS \& INTERFACES 11.7 (2019): 7415-7422.
Altan, Ali I., and Chen, Jian. “In situ chemical probing of hole defects and cracks in graphene at room temperature.” NANOSCALE 10.23 (2018): 11052-11063.
Banisadr, Seyedali, and Chen, Jian. “Infrared actuation-induced simultaneous reconfiguration of surface color and morphology for soft robotics.” SCIENTIFIC REPORTS 7. (2017).
Oyefusi, Adebola, and Chen, Jian. “Reprogrammable Chemical 3D Shaping for Origami, Kirigami, and Reconfigurable Molding.” ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 56.28 (2017): 8250-8253.
Kohlmeyer, Ryan R., Buskohl, Philip R., Deneault, James R., Durstock, Michael F., Vaia, Richard A., and Chen, Jian. “Shape-Reprogrammable Polymers: Encoding, Erasing, and Re-Encoding.” ADVANCED MATERIALS 26.48 (2014): 8114-8119.
Kohlmeyer, Ryan R., and Chen, Jian. “Wavelength-Selective, IR Light-Driven Hinges Based on Liquid CrystallineElastomer Composites.” ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 52.35 (2013): 9234-9237.
Chen, Jian. “Actuators and Infrared Sensors Based on Carbon Nanotube-Polymer Composites.” Carbon Nanotube-Polymer Composites. Ed. Tasis, Dimitrios. Royal Society of Chemistry, (2013): 22-50.
Kohlmeyer, Ryan R., Lor, Maika, and Chen, Jian. “Remote, Local, and Chemical Programming of Healable Multishape MemoryPolymer Nanocornposites.” NANO LETTERS 12.6 (2012): 2757-2762.
Kohlmeyer, Ryan R., Lor, Maika, Deng, Jian, Liu, Haiying, and Chen, Jian. “Preparation of stable carbon nanotube aerogels with high electricalconductivity and porosity.” CARBON 49.7 (2011): 2352-2361.
Kohlmeyer, Ryan R., Javadi, Alireza, Pradhan, Basudev, Pilla, Srikanth, Setyowati, Kristina, Chen, Jian, and Gong, Shaoqin. “Electrical and Dielectric Properties of Hydroxylated CarbonNanotube-Elastomer Composites.” JOURNAL OF PHYSICAL CHEMISTRY C 113.41 (2009): 17626-17629.
Pradhan, Basudev, Kohlmeyer, Ryan R., Setyowati, Kristina, and Chen, Jian. “Electron doping of small-diameter carbon nanotubes with exohedralfullerenes.” APPLIED PHYSICS LETTERS 93.22 (2008).
Yang, Liqiang, Setyowati, Kristina, Li, An, Gong, Shaoqin, and Chen, Jian. “Reversible infrared actuation of carbon nanotube-liquid crystallineelastomer nanocomposites.” ADVANCED MATERIALS 20.12 (2008): 2271+.
Pradhan, Basudev, Setyowati, Kristina, Liu, Haiying, Waldeck, David H., and Chen, Jian. “Carbon nanotube - Polymer nanocomposite infrared sensor.” NANO LETTERS 8.4 (2008): 1142-1146.
Setyowati, Kristina, Piao, Ming J., Chen, Jian, and Liu, Haiying. “Carbon nanotube surface attenuated infrared absorption.” APPLIED PHYSICS LETTERS 92.4 (2008).
Sankapal, Babasaheb R., Setyowati, Kristina, Chen, Jian, and Liu, Haiying. “Electrical properties of air-stable, iodine-dopedcarbon-nanotube-polymer composites.” APPLIED PHYSICS LETTERS 91.17 (2007).
Chen, Jian, Xue, Cuihua, Ramasubramaniam, Rajagopal, and Liu, Haiying. “A new method for the preparation of stable carbon nanotube organogels.” CARBON 44.11 (2006): 2142-2146.
Chen, Jian, Ramasubramaniam, R, Xue, C, and Liu, H. “A versatile, molecular engineering approach to simultaneously enhanced,multifunctional carbon-nanotube-polymer composites.” ADVANCED FUNCTIONAL MATERIALS 16.1 (2006): 114-119.
Ramasubramaniam, R, Chen, Jian, and Liu, HY. “Homogeneous carbon nanotube/polymer composites for electricalapplications.” APPLIED PHYSICS LETTERS 83.14 (2003): 2928-2930.
Chen, Jian, Liu, HY, Weimer, WA, Halls, MD, Waldeck, DH, and Walker, GC. “Noncovalent engineering of carbon nanotube surfaces by rigid, functionalconjugated polymers.” JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 124.31 (2002): 9034-9035.
Chen, Jian, and Weimer, WA. “Room-temperature assembly of directional carbon nanotube strings.” JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 124.5 (2002): 758-759.
Chen, Jian, Dyer, MJ, and Yu, MF. “Cyclodextrin-mediated soft cutting of single-walled carbon nanotubes.” JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 123.25 (2001): 6201-6202.
Chen, Jian, Rao, AM, Lyuksyutov, S, Itkis, ME, Hamon, MA, Hu, H, Cohn, RW, Eklund, PC, Colbert, DT, Smalley, RE, and Haddon, RC. “Dissolution of full-length single-walled carbon nanotubes.” JOURNAL OF PHYSICAL CHEMISTRY B 105.13 (2001): 2525-2528.
Rao, AM, Chen, Jian, Richter, E, Schlecht, U, Eklund, PC, Haddon, RC, Venkateswaran, UD, Kwon, YK, and Tomanek, D. “Effect of van der Waals interactions on the Raman modes in single walledcarbon nanotubes.” PHYSICAL REVIEW LETTERS 86.17 (2001): 3895-3898.
Andrews, R, Jacques, D, Rao, AM, Derbyshire, F, Qian, D, Fan, X, Dickey, EC, and Chen, Jian. “Continuous production of aligned carbon nanotubes: a step closer tocommercial realization.” CHEMICAL PHYSICS LETTERS 303.5-6 (1999): 467-474.
Chen, Jian, Hamon, MA, Hu, H, Chen, YS, Rao, AM, Eklund, PC, and Haddon, RC. “Solution properties of single-walled carbon nanotubes.” SCIENCE 282.5386 (1998): 95-98.

(selected from 61 publications with over 6500 citations; *as corresponding author)